Detecting subtle hydrochemical anomalies with multivariate statistics: an example from ‘homogeneous’ groundwaters in the Great Artesian Basin,Australia     

Bethany O'Shea  Jerzy Jankowski 《水文研究》2006,20(20):4317-4333

The major ion composition of Great Artesian Basin groundwater in the lower Namoi River valley is relatively homogeneous in chemical composition. Traditional graphical techniques have been combined with multivariate statistical methods to determine whether subtle differences in the chemical composition of these waters can be delineated. Hierarchical cluster analysis and principal components analysis were successful in delineating minor variations within the groundwaters of the study area that were not visually identified in the graphical techniques applied. Hydrochemical interpretation allowed geochemical processes to be identified in each statistically defined water type and illustrated how these groundwaters differ from one another. Three main geochemical processes were identified in the groundwaters: ion exchange, precipitation, and mixing between waters from different sources. Both statistical methods delineated an anomalous sample suspected of being influenced by magmatic CO₂ input. The use of statistical methods to complement traditional graphical techniques for waters appearing homogeneous is emphasized for all investigations of this type. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

Optical Spectroscopy of Comet C/2000 WM1 (LINEAR) at the Guillermo Harro Astrophysical Observatory in Mexico     

Churyumov  Klim I.  Luk'yanyk  Igor V.  Berezhnoi  Alexei A.  Chavushyan  Vahram H.  Sandoval  Lourdes S.  Palma  Alejandro A. 《Earth, Moon, and Planets》2002,90(1-4):361-368

We present a preliminary analysis of medium resolution optical spectra of comet C/2000 WM1 (LINEAR) obtained on 22 November 2001. Theemission lines of the molecules C₂, C₃, CN, NH₂,H₂O⁺ and presumably CO (Asundi and triplet bands) and C₂ ^-were identified in these spectra. By analysing the brightnessdistributions of the C₂, C₃, CN emission lines along theslit of the spectrograph we determined some physical parameters of theseneutrals, such as their lifetimes and expansion velocities inthe coma. The Franck–Condon factors for the CO Asundi bands and C₂ ^- bands were calculated using a Morse potential model.  相似文献   

水氯镁石脱水反应的热力学计算   总被引：4，自引：0，他引：4       下载免费PDF全文

景燕  马培华  褚敏雄 《盐湖研究》1999,7(4):15-22

水氯镁石脱水制备无水氯化镁是一个多反应的复杂过程,文中对水氯镁石脱水制备无水氯化镁过程中可能存在的化学反应的热力学各函数进行了计算,对脱水反应机理进行探讨,并为生产提供理论依据  相似文献   

Grigg-Skjellerup彗星新生离子激发低频电磁波性质          下载免费PDF全文

曹晋滨 《地球物理学报》1998,41(5):601-608

本文运用磁场的最小方差分析法和磁场-电子密度的相关分析法分析了欧洲空间局Giotto飞船对P／Grigg-Skjellerup（简称G-S）彗星弓激波附近磁场和电子能流的部分观测数据．结果表明彗星附近存在大量的频率靠近新生水族离子回旋频率的波动,它们是由彗星新生水族离子环流激发的低频左旋电磁波．波在近似平行于磁场方向传播,斜传播角小于15°．电子数据和磁场数据相关分析表明即使在离彗星很远的地方仍然存在压缩波．  相似文献   

Silicate and carbonate weathering in the drainage basins of the Ganga-Ghaghara-Indus head waters: Contributions to major ion and Sr isotope geochemistry   总被引：1，自引：0，他引：1  

S. Krishnaswami  Sunil K. Singh 《Journal of Earth System Science》1998,107(4):283-291

The role of silicate and carbonate weathering in contributing to the major cation and Sr isotope geochemistry of the headwaters of the Ganga-Ghaghara-Indus system is investigated from the available data. The contributions from silicate weathering are determined from the composition of granites/ gneisses, soil profiles developed from them and from the chemistry of rivers flowing predominantly through silicate terrains. The chemistry of Precambrian carbonate outcrops of the Lesser Himalaya provided the data base to assess the supply from carbonate weathering. Mass balance calculations indicate that on an average ∼ 77% (Na + K) and ∼ 17% (Ca + Mg) in these rivers is of silicate origin. The silicate Sr component in these waters average ∼40% and in most cases it exceeds the carbonate Sr. The observations that (i) the⁸⁷Sr/⁸⁶Sr and Sr/Ca in the granites/gneisses bracket the values measured in the head waters; (ii) there is a strong positive correlation between⁸⁷Sr/⁸⁶Sr of the rivers and the silicate derived cations in them, suggest that silicate weathering is a major source for the highly radiogenic Sr isotope composition of these source waters. The generally low⁸⁷Sr/⁸⁶Sr (< 0.720) and Sr/Ca (∼ 0.2 nM/ μM) in the Precambrian carbonate outcrops rules them out as a major source of Sr and⁸⁷Sr/⁸⁶Sr in the headwaters on a basin-wide scale, however, the high⁸⁷Sr/⁸⁶Sr (∼ 0.85) in a few of these carbonates suggests that they can be important for particular streams. The analysis of⁸⁷Sr/⁸⁶Sr and Ca/Sr data of the source waters show that they diverge from a low⁸⁷Sr/⁸⁶Sr and low Ca/Sr end member. The high Ca/Sr of the Precambrian carbonates precludes them from being this end member, other possible candidates being Tethyan carbonates and Sr rich evaporite phases such as gypsum and celestite. The results of this study should find application in estimating the present-day silicate and carbonate weathering rates in the Himalaya and associated CO₂ consumption rates and their global significance.  相似文献   

Estimation of groundwater recharge using the chloride mass-balance method, Pingtung Plain, Taiwan   总被引：4，自引：0，他引：4  

Cheh-Shyh Ting  Tienfuan Kerh  Chiu-Jung Liao 《Hydrogeology Journal》1998,6(2):282-292

 Due to rapid economic growth in the Pingtung Plain of Taiwan, the use of groundwater resources has changed dramatically. Over-pumping of the groundwater reservoir, which lowers hydraulic heads in the aquifers, is not only affecting the coastal area negatively but has serious consequences for agriculture throughout the plain. In order to determine the safe yield of the aquifer underlying the plain, a reliable estimate of groundwater recharge is desirable. In the present study, for the first time, the chloride mass-balance method is adopted to estimate groundwater recharge in the plain. Four sites in the central part were chosen to facilitate the estimations using the ion-chromatograph and Thiessen polygon-weighting methods. Based on the measured and calculated results, in all sites, including the mountain and river boundaries, recharge to the groundwater is probably 15% of the annual rainfall, excluding recharge from additional irrigation water. This information can improve the accuracy of future groundwater-simulation and management models in the plain. Received, April 1996 Revised, March 1997, November 1997 Accepted, March 1998  相似文献   

A spectrophotometric measurement of soil cation exchange capacity based on cobaltihexamine chloride absorbance     

Delphine Aran  Armand Maul  Jean-Franois Masfaraud 《Comptes Rendus Geoscience》2008,340(12):865-871

Among numerous methods for cation exchange capacity (CEC) determination for soils and sediments, the cobaltihexamine chloride method is frequently used due to its ability to measure CEC at soil pH. After exchange with Co(NH₃)₆³⁺ ions, CEC is estimated via the measurement of the Co remaining in solution. The modified method proposed allows a more rapid determination of CEC based on the measurement of the absorbance at 472 nm of the cobaltihexamine chloride solution before and after exchange. This method has been applied to various soil's horizons from four sites, selected to cover a wide range of CEC and pH values. The model obtained allows one to calculate CEC from absorbance at 472 nm with 95% confidence intervals. As CEC is of relevant meaning in agronomical and environmental purposes, and more recently in ecotoxicological studies, this modified method can be proposed as a rapid test for CEC evaluation.  相似文献   

Zircon M257 ‐ a Homogeneous Natural Reference Material for the Ion Microprobe U‐Pb Analysis of Zircon     

Lutz Nasdala  Wolfgang Hofmeister  Nicholas Norberg  James M. Martinson  Fernando Corfu  Wolfgang Dörr  Sandra L. Kamo  Allen K. Kennedy  Andreas Kronz  Peter W. Reiners  Dirk Frei  Jan Kosler  Yusheng Wan  Jens Götze  Tobias Häger  Alfred Kröner  John W. Valley 《Geostandards and Geoanalytical Research》2008,32(3):247-265

We introduce and propose zircon M257 as a future reference material for the determination of zircon U‐Pb ages by means of secondary ion mass spectrometry. This light brownish, flawless, cut gemstone specimen from Sri Lanka weighed 5.14 g (25.7 carats). Zircon M257 has TIMS‐determined, mean isotopic ratios (2s uncertainties) of 0.09100 ± 0.00003 for ²⁰⁶pb/²³⁸U and 0.7392 ± 0.0003 for ²⁰⁷pb/²³⁵U. Its ²⁰⁶pb/²³⁸U age is 561.3 ± 0.3 Ma (unweighted mean, uncertainty quoted at the 95% confidence level); the U‐Pb system is concordant within uncertainty of decay constants. Zircon M257 contains ～ 840 μg g^?1 U (Th/U ～ 0.27). The material exhibits remarkably low heterogeneity, with a virtual absence of any internal textures even in cathodoluminescence images. The uniform, moderate degree of radiation damage (estimated from the expansion of unit‐cell parameters, broadening of Raman spectral parameters and density) corresponds well, within the “Sri Lankan trends”, with actinide concentrations, U‐Pb age, and the calculated alpha fluence of 1.66 × 10¹⁸ g^?1. This, and a (U+Th)/He age of 419 ± 9 Ma (2s), enables us to exclude any unusual thermal history or heat treatment, which could potentially have affected the retention of radiogenic Pb. The oxygen isotope ratio of this zircon is 13.9%o VSMOW suggesting a metamorphic genesis in a marble or calc‐silicate skarn.  相似文献   

新型抗水氯氧镁水泥防渗渠在自然环境的水化产物、相转变规律及其对强度的影响          下载免费PDF全文

石天阳  余红发  麻海燕  李颖 《盐湖研究》2021,29(3):38-46, 55

氯氧镁水泥(Magnesium oxychloride cement, MOC)具有快凝、早强、高强、防火和不腐蚀玻璃纤维等优点,非常适合于制作玻璃纤维增强薄壁制品,在农业灌溉工程中具有良好的应用前景。采用XRD和TOPAS分析了新型抗水氯氧镁水泥制成内蒙古防渗渠的物相组成,探讨了氯氧镁水泥制品在自然环境的水化产物与相转变规律、以及相组成对强度的影响。结果表明,在水分缺少的条件下,氯氧镁水泥的水化产物主要为5Mg(OH)_2·MgCl_2·8H_2O(5·1·8)和Mg(OH)_2;在水分充足的条件下,水化产物主要为Mg(OH)_2和5·1·8,碳化产物为碳化氯氧化镁Mg(OH)_2·MgCl_2·2MgCO_3·6H_2O(1·1·2·6)和水菱镁矿4MgCO_3·Mg(OH)_2·4H_2O(4·1·4)。水化产物对强度有促进作用,而碳化产物会降低强度。通过10年的工程环境考验,证明新型氯氧镁水泥制品在环境中能够保持主要强度相5·1·8的稳定性,具有良好的长期力学性能。  相似文献   

实验研究不同盐离子对水分子拉曼效应的影响   总被引：3，自引：0，他引：3  

陈勇  周瑶琪  查明  王爱国 《地球化学》2008,37(1):22-26

对流体包裹体中常见的几种盐水溶液进行了拉曼光谱分析.采用了频移参数描述水分子拉曼峰的形变强度,并讨论了频移参数与盐度之间的关系.实验分析结果表明,盐度越大,频移参数越大,水分子拉曼峰形变越大.对频移参数曲线斜率分析显示,盐类对水分子拉曼峰偏移程度影响的强弱顺序为NaCl＞Na2SO4＞NaHCO3＞Na2CO3.讨论了不同阳离子和阴离子对水伸缩振动拉曼峰的影响,结果表明,高价阳离子的影响明显高于低价阳离子;而阴离子对水拉曼峰影响的强弱顺序初步确定为Cl-≈SO2-4-＞HCO-3＞CO2-3≈NO-3.  相似文献